Formation of a spiral-shaped inorganic-organic hybrid chain, [CuII(2,2′-bipy)(H2O)2Al(OH)6Mo6O18]nn-:: Influence of intra- and interchain supramolecular interactions

被引：146

作者：

Shivaiah, V ^{[1
]}

Nagaraju, M ^{[1
]}

Das, SK ^{[1
]}

机构：

[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

INORGANIC CHEMISTRY | 2003年 / 42卷 / 21期

关键词：

CLUSTERS; CHEMISTRY; SOLIDS;

D O I：

10.1021/ic034581f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel chainlike coordination polymer [Cu-II(2,2'-bipy)(H2O)(2)Al-(OH)(6)Mo6O18](n)(n-), formed from a heteropolyanion [Al(OH)(6)Mo6O18](3-) as a building unit and a copper(II) complex fragment, [Cu-II(2,2'-bipy)(H2O)(2)](2+), as a linker, provides the first example of an extended structure based on an Anderson type of polyanion and a transition metal complex with organic ligand. The intra- and interchain O-H...O hydrogen-bonding interactions are seemingly responsible for the spiral shape of this chain. Crystal data: triclinic space group P (1) over bar, a = 11.2253(18) Angstrom, b = 14.5194(17) Angstrom, c = 15.2672(10) Angstrom, alpha = 112.191(8)degrees, beta = 106.693(9)degrees, gamma = 93.916(13)degrees, and Z = 2.

引用

页码：6604 / 6606

页数：3

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