Vibrational energy relaxation of oxygen in liquid mixtures with argon

被引：46

作者：

Everitt, KF ^{[1
]}

Skinner, JL

机构：

[1] Univ Wisconsin, Inst Theoret Chem, Madison, WI 53706 USA

[2] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1999年 / 110卷 / 09期

关键词：

D O I：

10.1063/1.478330

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We calculate the vibrational energy relaxation rate constants for oxygen molecules in oxygen/argon liquid mixtures of various mole fractions at 77 K. Our results are uniformly about a factor of 5 larger than experimental values, which are in the range of 100 s(-1). When the mole fraction-dependent results are scaled by their values for neat oxygen, theory and experiment are in excellent agreement. (C) 1999 American Institute of Physics. [S0021-9606(99)50109-8].

引用

页码：4467 / 4470

页数：4

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