Self-assembly of discrete metallosupramolecular luminophores

被引：85

作者：

Cooke, Michael W. ^{[1
]}

Chartrand, Daniel ^{[1
]}

Hanan, Garry S. ^{[1
]}

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3T 1J4, Canada

来源：

COORDINATION CHEMISTRY REVIEWS | 2008年 / 252卷 / 8-9期

基金：

加拿大自然科学与工程研究理事会;

关键词：

metal-directed self-assembly; metallosupramolecular chemistry; luminescence; transition metal ions; energy transfer; electron transfer;

D O I：

10.1016/j.ccr.2008.01.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review examines the metal-directed self-assembly of luminescent metallosupramolecular structures. A brief overview of the self-assembly process is followed by a discussion of the various types of assemblies based on the nuclearity of the luminophore: dinuclear, trinuclear, tetranuclear and higher nuclearity species. The final assemblies are discussed in light of their synthesis, their photophysical properties, and the role that the metal ion plays: (i) a purely structural role, or (ii) a structural and functional role. While some step-wise syntheses are mentioned, the majority of the polynuclear complexes presented herein are built up by a self-assembly process. Whenever possible, the potential applications of the luminescent metallosupramolecular assemblies are presented and discussed. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：903 / 921

页数：19

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