Synthesis of CETBz-TTF and CESBz-TTF: Preparation, structural and physical properties of their radical salts with paramagnetic Cu(II) complex anions

被引：4

作者：

Boudiba, L

Gouasmia, AK

Kaboub, L

Cador, O

Ouahab, L ^{[1
]}

Fabre, JM

机构：

[1] Univ Rennes 1, Inst Chim Rennes, LCSIM, CNRS UMR 6511, F-35042 Rennes, France

[2] ENSCM, UMR 5076, F-34296 Montpellier, France

来源：

SYNTHETIC METALS | 2005年 / 150卷 / 03期

关键词：

single-crystal growth; magnetic measurements; X-ray diffraction; organic conductors based on radical cation;

D O I：

10.1016/j.synthmet.2005.03.002

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

CETBz-TTF (4.5-bis(cyanoethylthio)benzo-tetrathiafulvalene) and CESBz-TTF (4,5-bis(eyanoethylseleno)benzo-tetrathiafulvalene) 5 have been synthesized from cyano precursor via a cross-coupling reaction. Radical salts with paramagnetic Cu(II) complex anions, such as (CETBz-TTF)(2)CuCl4 6 and (CESBz-TTF)(2)CuCl4 7 have been prepared. X-ray crystal structure and physical properties of these new compounds are presented. (c) 2005 Elsevier B.V. All rights reserved.

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页码：317 / 320

页数：4

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