Syntheses and crystal structures of isomalononitrile dithiolato complexes (Bu(4)N)(2)Zn(i-mnt)(2) and (Et(4)N)(2)Pd(i-mnt)(2)

被引：13

作者：

Long, DL

Hou, HW

Xin, XQ

Yu, KB

Luo, BS

Chen, LR

机构：

[1] NANJING UNIV,INST COORDINAT CHEM,STATE KEY LAB COORDINAT CHEM,NANJING 210093,PEOPLES R CHINA

[2] ACAD SINICA,CHENGDU CTR ANAL & DETERMINAT,CHENGDU 610041,PEOPLES R CHINA

[3] WUHAN UNIV,ANAL & TESTING CTR,WUHAN 430072,PEOPLES R CHINA

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1996年 / 38卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

synthesis; X-ray structure; isomalononitrile dithiolate; zinc; palladium;

D O I：

10.1080/00958979608022686

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two isomalononitrile dithiolato complexes, (Bu(4)N)(2)Zn(i-mnt)(2) (1) and (Et(4)N)(2)Pd(i-mnt)(2) (2) were synthesized and characterized by elemental analysis, IR and electronic spectroscopy, Their structures have been crystallographically determined. The reaction of (Et(4)N)(2)Pd(i-mnt)(2) (2) with (Et(4)N)(2)WS4 gives (Et(4)N)(2)WS4Pd(i-mnt).

引用

页码：15 / 24

页数：10

共 24 条

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Coucouvanis D., 1979, PROG INORG CHEM, V26, P301, DOI [10.1002/9780470166277.ch5, DOI 10.1002/9780470166277.CH5]

[2]

COUCOUVANIS D, 1975, INORG CHEM, V13, P1191

[3]

DIETRICH H, 1981, MAKROMOL CHEM, V182, P2371

[4] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A 1,1-DITHIOLATE CLUSTER ANION CONTAINING AN AG61 OCTAHEDRON [AG61(S2C=C(CN)2)6]6- [J].