Iron-catalyzed homo-coupling of simple and functionalized arylmagnesium reagents

被引：179

作者：

Cahiez, G ^{[1
]}

Chaboche, C ^{[1
]}

Mahuteau-Betzer, F ^{[1
]}

Ahr, M ^{[1
]}

机构：

[1] ESCOM, UCP, CNRS, UMR 8123,Lab SOSCO, F-95092 Cergy Pontoise, France

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 10期

关键词：

D O I：

10.1021/ol050340v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Iron-catalyzed homo-coupling of simple and functionalized arylmagnesium reagents is described. The reaction is highly chemoselective (CN, COOEt and NO2 groups are tolerated). The procedure was used to perform intramolecular couplings. This cyclization reaction is the key step of the total synthesis of the N-methylcrinasiadine.

引用

页码：1943 / 1946

页数：4

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