Heck reaction using nickel/TPPTS catalyst and inorganic base on supported ethylene glycol phase

被引：38

作者：

Bhanage, BH ^{[1
]}

Zhao, FY ^{[1
]}

Shirai, M ^{[1
]}

Arai, M ^{[1
]}

机构：

[1] Tohoku Univ, Inst Chem React Sci, Aoba Ku, Sendai, Miyagi 9808577, Japan

来源：

CATALYSIS LETTERS | 1998年 / 54卷 / 04期

关键词：

supported liquid film catalyst; Ni/TPPTS catalyst; Heck reaction; biphasic catalysis;

D O I：

10.1023/A:1019077300108

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vinylation of butyl acrylate and halobenzene was studied using the Ni/TPPTS (TPPTS: triphenylphosphine trisulfonate, sodium salt) catalyst immobilized on silica. Inorganic base such as potassium acetate was found to be effective. The catalyst stability and recycle ability have been studied in the temperature range of 130-150 degrees C.

引用

页码：195 / 198

页数：4

共 14 条

[1] First palladium-catalyzed Heck reactions with efficient colloidal catalyst systems [J].

Beller, M ;

Fischer, H ;

Kuhlein, K ;

Reisinger, CP ;

Herrmann, WA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 520 (1-2) :257-259

[2] NICKEL-CATALYZED COUPLING OF ACTIVATED ALKENES WITH ORGANIC HALIDES [J].

BOLDRINI, GP ;

SAVOIA, D ;

TAGLIAVINI, E ;

TROMBINI, C ;

RONCHI, AU .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 301 (03) :C62-C64

[3] RECENT DEVELOPMENTS AND NEW PERSPECTIVES IN THE HECK REACTION [J].

CABRI, W ;

CANDIANI, I .

ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (01) :2-7

[4] FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB [J].

DE MEIJERE, A ;

MEYER, FE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) :2379-2411

[5]

de Meijere A, 1994, ANGEW CHEM, V106, P2473, DOI DOI 10.1002/ANGE.19941062307

[6] Palladacycles: Efficient new catalysts for the Heck vinylation of aryl halides [J].

Herrmann, WA ;

Brossmer, C ;

Reisinger, CP ;

Riermeier, TH ;

Ofele, K ;

Beller, M .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (08) :1357-1364

[7] Organometallic homogeneous catalysis - Quo vadis? [J].

Herrmann, WA ;

Cornils, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (10) :1048-1067

[8]

HERRMANN WA, 1997, ANGEW CHEM, V109, P1074

[9] Ni(0) catalyzed reactions of aryl and vinyl halides with alkenes and alkynes [J].

Iyer, S ;

Ramesh, C ;

Ramani, A .

TETRAHEDRON LETTERS, 1997, 38 (49) :8533-8536

[10] THE VINYLATION OF BROMOBIPHENYLS USING HOMOGENEOUS NICKEL-CATALYSTS [J].

KELKAR, AA ;

HANAOKA, T ;

KUBOTA, Y ;

SUGI, Y .

CATALYSIS LETTERS, 1994, 29 (1-2) :69-75

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