vic-Diacrylic ester porphyrins as starting materials for monobenzoporphyrin and opp-dibenzoporphyrin syntheses

被引：5

作者：

Boudif, A ^{[1
]}

Gimenez, S

Loock, B

Momenteau, M

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

[2] Univ Paris 11, Inst Curie Rech, Unite Mixte Rech, CNRS, F-91405 Orsay, France

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1998年 / 76卷 / 08期

关键词：

tripyrrane; diformylpyrrole; vic-diacrylic ester porphyrin; 3+1" synthesis methodology; monobenzoporphyrin; opp-dibenzoporphyrin; photosensitizer;

D O I：

10.1139/cjc-76-8-1215

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of a bis(vic-diacrylic ester) porphyrin using the "3+1" methodology is described. A two-step procedure is used to convert the vic-diacrylic ester porphyrin and the bis(vic-diacrylic ester) porphyrin to the monobenzoporphyrin and the opp-dibenzoporphyrin, respectively. Characterization of the compounds by H-1 NMR and UV-visible spectroscopies is also discussed.

引用

页码：1215 / 1219

页数：5

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[4]

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