Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [γ-SIW10O36]8-:: A totally inorganic oxygen-evolving catalyst

被引：513

作者：

Sartorel, Andrea ^{[1
,2
]}

Carraro, Mauro

Scorrano, Gianfranco

De Zorzi, Rita ^{[3
]}

Geremia, Silvano ^{[1
,2
,3
]}

McDaniel, Neal D. ^{[4
]}

Bernhard, Stefan ^{[4
]}

Bonchio, Marcella ^{[1
,2
]}

机构：

[1] ITM, CNR, I-35131 Padua, Italy

[2] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy

[3] Univ Trieste, Dipartimento Sci Chim, Ctr Eccellenzia Biocristallog, I-34127 Trieste, Italy

[4] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 15期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/ja077837f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solid state and solution evidence confirms the embedding of an adamantane like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h(-1).

引用

页码：5006 / +

页数：3

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