Sources of error in using silver/silver chloride electrodes to monitor chloride activity in concrete

被引:58
作者
Atkins, CP
Carter, MA
Scantlebury, JD
机构
[1] UMIST, Dept Civil & Construct Engn, Manchester M60 1QD, Lancs, England
[2] Mott MacDonald, Altrincham WA14 1ES, England
[3] UMIST, Ctr Corros & Protect, Manchester M60 1QD, Lancs, England
关键词
temperature; corrosion; chloride; concrete; bromide;
D O I
10.1016/S0008-8846(01)00544-0
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The silver/silver chloride electrode is discussed as a chloride-monitoring device in concrete rather than as a reference electrode. The effects of temperature, bromide ions, and applied potential fields on the reliability and accuracy of these electrodes are evaluated. The effect of temperature is assessed using a novel mathematical approach and the other two effects are examined experimentally. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1207 / 1211
页数:5
相关论文
共 11 条
[1]   Monitoring chloride concentrations in hardened cement pastes using ion selective electrodes [J].
Atkins, CP ;
Scantlebury, JD ;
Nedwell, PJ ;
Blatch, SP .
CEMENT AND CONCRETE RESEARCH, 1996, 26 (02) :319-324
[2]  
ATKINSON BW, 1995, ERCOFTAC SER, V1, P1
[3]  
BARD AJ, 1980, ELECTROCHEMICAL METH, P24
[4]  
*CRC, 1978, CRC HDB CHEM PHYS, pB254
[5]  
FINCHAM AA, 1984, BASIC MARINE BIOL
[6]  
IVES DJG, 1961, REFERENCE ELECT THEO
[7]  
NEVILLE AM, 1995, PROPERTIES CONCRETE, P346
[8]   PURIFICATION OF SODIUM CHLORIDE AND POTASSIUM CHLORIDE FOR USE IN ELECTROCHEMICAL WORK, AND THE DETERMINATION OF SMALL AMOUNTS OF BROMIDE [J].
PINCHING, GD ;
BATES, RG .
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS, 1946, 37 (05) :311-319
[9]  
SHRIER LL, 1979, CORROSION, V1
[10]  
WEAST RC, 1981, HDB CHEM PHYSICS