Highly efficient Ru-pseudohalide catalysts for olefin metathesis

被引：154

作者：

Conrad, JC ^{[1
]}

Parnas, HH ^{[1
]}

Snelgrove, JL ^{[1
]}

Fogg, DE ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 34期

关键词：

D O I：

10.1021/ja042736s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ruthenium alkylidene complexes containing one aryloxide "pseudohalide" ligand catalyze ring-closing metathesis of diene and ene-yne substrates with exceptionally high efficiency. Chromatographic removal of Ru residues is unexpectedly facile, offering a convenient means of isolating pure organic products in high yields. Copyright © 2005 American Chemical Society.

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页码：11882 / 11883

页数：2

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