Diamond-shaped heterometallic complexes of Iron(II) and Copper(I) bridged by cyanide groups

被引：20

作者：

Darensbourg, DJ ^{[1
]}

Lee, WZ ^{[1
]}

Adams, MJ ^{[1
]}

Larkins, DL ^{[1
]}

Reibenspies, JH ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 07期

关键词：

D O I：

10.1021/ic981419h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tetrametallic, diamond-shaped heterometallic complexes of iron(II) and Cu(I), [eta(5)-C5H5Fe(CO)(mu-CN)(2)Cu(PCy3)(x)](2), where x = 1 or 2, have been synthesized and fully characterized. X-ray crystallography reveals the geometrics about the copper(I) centers to be trigonal (x = 1) and tetrahedral (x = 2). Although the Fe-C=N bond angles are nearly linear, the Cu-N=C angles deviate significantly from linearity.

引用

页码：1378 / +

页数：3

共 42 条

[1] BEER PD, 1996, J CHEM SOC CHEM COMM, P689
[2] Synthesis and characterization of molecular rectangles based upon rhenium Thiolate dimers
Benkstein, KD
Hupp, JT
Stern, CL
[J]. INORGANIC CHEMISTRY, 1998, 37 (21) : 5404 - +
[3] CYANO-BRIDGED ORGANOTIN COMPOUNDS - CRYSTAL-STRUCTURE OF A TRINUCLEAR DIANION CONTAINING A NEARLY LINEAR-ARRAY OF 9 ATOMS
CARINI, C
PELIZZI, C
PELIZZI, G
PREDIERI, G
TARASCONI, P
VITALI, F
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (08) : 613 - 614
[4] COFFEY CE, 1963, J INORG NUCL CHEM, V25, P179
[5] COUTAKES SM, 1998, ORGANOMETALLICS, V17, P3633
[6] Cyanide-bridged heterobimetallic complexes of the group 6 metal carbonyls and copper(I). X-ray structures of (CO)(5)MCNCu(PPh(3))(3) (M=Cr, W) derivatives
Darensbourg, DJ
Yoder, JC
Holtcamp, MW
Klausmeyer, KK
Reibenspies, JH
[J]. INORGANIC CHEMISTRY, 1996, 35 (16) : 4764 - 4769
[7] DUNBAR KR, 1997, PROG INORG CHEM, V93, P1243
[8] EMRI J, 1976, J ORGANOMET CHEM, V112, P235
[9] EMERGENCE OF A CNH AND CYANO COMPLEX BASED ORGANOMETALLIC CHEMISTRY
FEHLHAMMER, WP
FRITZ, M
[J]. CHEMICAL REVIEWS, 1993, 93 (03) : 1243 - 1280
[10] OCTAHEDRO OCTAHEDRA AND TETRAHEDRA .2. TETRANUCLEAR TO HEPTANUCLEAR CARBONYL(CYANO)CHROMATO, CARBONYL(CYANO) MOLYBDATO AND CARBONYL(CYANO) TUNGSTATO COMPLEXES OF 3D-METALS
FRITZ, M
RIEGER, D
BAR, E
BECK, G
FUCHS, J
HOLZMANN, G
FEHLHAMMER, WP
[J]. INORGANICA CHIMICA ACTA, 1992, 198 : 513 - 526

← 1 2 3 4 5 →