Study on cycling performances of lithium-ion polymer cells assembled by in situ chemical cross-linking with star-shaped siloxane acrylate

被引：14

作者：

Kim, Wanju ^{[1
]}

Cho, Jeong-Ju ^{[2
]}

Kang, Yongku ^{[3
]}

Kim, Dong-Won ^{[1
]}

机构：

[1] Hanbat Natl Univ, Dept Appl Chem, Taejon 305719, South Korea

[2] LG Chem Ltd, Batteries R&D, Taejon 305380, South Korea

[3] Korea Res Inst Chem Technol, Adv Mat Div, Taejon 305600, South Korea

来源：

JOURNAL OF POWER SOURCES | 2008年 / 178卷 / 02期

关键词：

chemical cross-linking; cross-linking agent; gel polymer electrolyte; lithium-ion polymer cell; microporous membrane; star-shaped siloxane acrylate;

D O I：

10.1016/j.jpowsour.2007.07.050

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The chemically cross-linked gel polymer electrolytes supported by the microporous polyethylene membrane were prepared for application in lithium-ion polymer cells. The chemical cross-linking by star-shaped siloxane acrylate allowed to encapsulate an electrolyte solution in the porous membrane and also promote strong interfacial adhesion between the electrodes and the membrane. Lithium-ion polymer cells composed of a mesocarbon microbead anode and a lithium-cobalt oxide cathode were assembled by using in situ chemical cross-linking method, and their charge/discharge cycling performances were evaluated. Effect of the cross-linking agent content on cycling performances of the cells has been investigated. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：837 / 841

页数：5

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