Two unprecedented 3-connected three-dimensional networks of copper(I) triazolates: In situ formation of ligands by cycloaddition of nitriles and ammonia

被引：320

作者：

Zhang, JP ^{[1
]}

Zheng, SL ^{[1
]}

Huang, XC ^{[1
]}

Chen, XM ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 02期

关键词：

copper; cycloaddition; hydrothermal synthesis; N ligands; triazoles;

D O I：

10.1002/anie.200352627

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One-pot synthesis of 1,2,4-triazoles: Hydrothermal treatment of copper(II) ions, ammonia, and nitriles yielded two copper(I) triazolate coordination polymers, the structures of which have unearthed the unprecedented formation of triazolates through the cycloaddition of NH3 and RC≡N. The polymers exhibit novel network topologies based on trigonal nodes (see picture).

引用

页码：206 / 209

页数：4

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