Electrochemical trifluoromethylation of dimethyl acetylenedicarboxylate

被引：5

作者：

Dmowski, W

Biernacki, A

机构：

[1] Institute of Organic Chemistry, Polish Academy of Sciences, 01-224 Warsaw

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1996年 / 78卷 / 02期

关键词：

electrochemical trifluoromethylation; dimethyl acetylenedicarboxylate; trifluoroacetic acid; trifluoromethylmaleates; trifluoromethylsuccinate; NMR spectroscopy;

D O I：

10.1016/0022-1139(96)03443-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electrooxidation of trifluoroacetic acid in the presence of dimethyl acetylenedicarboxylate in an acetonitrile/water solution provided cis and trans dimethyl 2,3-bis(trifluoromethyl) maleates and dimethyl 2,2,3-tris (trifluoromethyl) succinate as the main products.

引用

页码：193 / 194

页数：2

共 15 条

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