Novel heterofluorene-based hosts for highly efficient blue electrophosphorescence at low operating voltages

被引:30
作者
Chen, Run-Feng [2 ]
Xie, Guo-Hua [1 ]
Zhao, Yi [1 ]
Zhang, Sheng-Lan [2 ]
Yin, Jun [2 ]
Liu, Shi-Yong [1 ]
Huang, Wei [2 ]
机构
[1] Jilin Univ, Coll Elect Sci & Engn, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
[2] NUPT, IAM, Key Lab Organ Elect & Informat Displays KOLED, Nanjing 210046, Peoples R China
基金
中国国家自然科学基金;
关键词
Organic light-emitting diodes; Host material; Heterofluorene; LIGHT-EMITTING-DIODES; OPTOELECTRONIC PROPERTIES; CONJUGATED COPOLYMER; TRANSPORT; POLYMER; PERFORMANCE; GAP;
D O I
10.1016/j.orgel.2011.05.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel concept for molecular design of blue host materials for phosphorescent OLEDs (PHOLEDs) by combining carbazole and heterofluorene via structurally mimicking 4,4'-N,N'-dicarbazole-biphenyl (CBP) was presented. The carbazole end-capped heterofluorenes (CzHFs) prepared accordingly in high yields, were found to be ideal hosts for blue PHOLEDs. At the brightness level of 1000 and 5000 cd m (2), the driving voltages are still lower than 4.5 V with the external quantum efficiencies retain as high as 18.1% and 16.8% respectively. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:1619 / 1624
页数:6
相关论文
共 39 条
[1]   Quantum-chemical design of host materials for full-color triplet emission [J].
Avilov, I ;
Marsal, P ;
Brédas, JL ;
Beljonne, D .
ADVANCED MATERIALS, 2004, 16 (18) :1624-+
[2]   Highly efficient phosphorescent emission from organic electroluminescent devices [J].
Baldo, MA ;
O'Brien, DF ;
You, Y ;
Shoustikov, A ;
Sibley, S ;
Thompson, ME ;
Forrest, SR .
NATURE, 1998, 395 (6698) :151-154
[3]   Polycarbazoles for plastic electronics [J].
Boudreault, Pierre-Luc T. ;
Beaupre, Serge ;
Leclerc, Mario .
POLYMER CHEMISTRY, 2010, 1 (02) :127-136
[4]   Poly(2,7-dibenzosilole): A blue light emitting polymer [J].
Chan, KL ;
McKiernan, MJ ;
Towns, CR ;
Holmes, AB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (21) :7662-7663
[5]   Spirobifluorene-based pyrazoloquinolines: efficient blue electroluminescent materials [J].
Chen, CH ;
Wu, FI ;
Shu, CF ;
Chien, CH ;
Tao, YT .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (10) :1585-1589
[6]   A general strategy for the facile synthesis of 2,7-dibromo-9-heterofluorenes [J].
Chen, RF ;
Fan, QL ;
Zheng, C ;
Huang, W .
ORGANIC LETTERS, 2006, 8 (02) :203-205
[7]   Synthesis, structure, and optoelectronic properties of phosphafluorene copolymers [J].
Chen, Run-Feng ;
Zhu, Rui ;
Fan, Qu-Li ;
Huang, Wei .
ORGANIC LETTERS, 2008, 10 (13) :2913-2916
[8]   Structural, electronic, and optical properties of 9-heterofluorenes: A quantum chemical study [J].
Chen, Run-Feng ;
Zheng, Chao ;
Fan, Qu-Li ;
huang, Wei .
JOURNAL OF COMPUTATIONAL CHEMISTRY, 2007, 28 (13) :2091-2101
[9]   Fluorene and silafluorene conjugated copolymer: A new blue light-emitting polymer [J].
Chen, Run-Feng ;
Fan, Qu-Li ;
Liu, Shu-Juan ;
Zhu, Rui ;
Pu, Kan-Yi ;
Huang, Wei .
SYNTHETIC METALS, 2006, 156 (18-20) :1161-1167
[10]   Germafluorene conjugated copolymer-synthesis and applications in blue-light-emitting diodes and host materials [J].
Chen RunFeng ;
Zhu Rui ;
Zheng Chao ;
Liu ShuJuan ;
Fan QuLi ;
Huang Wei .
SCIENCE IN CHINA SERIES B-CHEMISTRY, 2009, 52 (02) :212-218