A new tetraoxa-tetraaza macrobicyclic anthracenyl luminescent receptor: control of the receptor-substrate stoichiometry

被引:14
作者
Di Pietro, C
Guglielmo, G
Campagna, S [1 ]
Diotti, M
Manfredi, A
Quici, S
机构
[1] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy
[2] Univ Milan, Ctr CNR, I-20133 Milan, Italy
[3] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy
关键词
D O I
10.1039/a801329b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The luminescent receptor 1 incorporating anthracenyl groups as luminophores and a tetraoxa-tetraaza macrobicyclic receptor as the binding subunit has been synthesized and its interactions with Ca-II, investigated by fluorescence measurements, are reported. The receptor-substrate 1-Ca system is an example of multistability at the molecular level, triggered by a reversible modification of the receptor ability and evidenced by luminescence.
引用
收藏
页码:1037 / 1039
页数:3
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