A supramolecular tetradecanudear copper(II) polyoxotungstate

被引：111

作者：

Mialane, P

Dolbecq, A

Marrot, J

Rivière, E

Sécheresse, F

机构：

[1] Univ Versailles, Inst Lavoisier, IREM, UMR 8637, F-78035 Versailles, France

[2] Univ Paris 11, Inst Chim Mol Orsay, URA CNRS 420, Chim Inorgan Lab, F-91405 Orsay, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 30期

关键词：

copper; magnetism; polyanions; solid-state structures; tungsten;

D O I：

10.1002/anie.200351486

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four {SiW9O34} units enclose a 14 CuII cluster obtained through halide supramolecular assembly, leading to the polyanion containing the highest number of divalent metal cations (see picture; W blue, Si yellow, Br orange, Cu green, O red).

引用

页码：3523 / 3526

页数：4

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