Quantitative analysis of silicate glass in ceramic materials by the Rietveld method

被引:245
作者
Lutterotti, L
Ceccato, R
Dal Maschio, R
Pagani, E
机构
[1] Univ Trent, Dipartimento Ingn Mat, I-38050 Trent, Italy
[2] Maffei SPA, I-38100 Trent, Italy
来源
EPDIC 5, PTS 1 AND 2 | 1998年 / 278-2卷
关键词
silica-glass; XRD; Rietveld method; quantitative analysis; amorphous;
D O I
10.4028/www.scientific.net/MSF.278-281.87
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The modelling of silica glass, following the work of Le Bail [1], has been introduced in a Rietveld general procedure developed for quantitative phase analysis. The method approximates the amorphous phase as a nanocrystalline solid where the long-range order is lost. As pointed out by the same author, the model is not sufficient to describe exactly the amorphous structure. Moreover, from a fitting point of view, it provides nearly the same results as those obtained by reverse Monte Carlo simulation (RMC). This study shows how this approach can be successfully used to determine the amorphous fraction in ceramic materials containing a glassy phase. The "crystal structure" of silica, as determined by Le Bail [1], has been used, whereas the nanocrystalline behaviour is obtained using the line-broadening theory reported in [2] with a crystallite size of about one cell. The method has been tested on synthetic mixtures and ceramic-wars materials using X-ray diffraction. It provides an accurate, fast and standardless method of analysis suitable for quality and research controls. Other amorphous phases can be analysed providing a "crystal structure" model previously refined on a sufficiently pure sample.
引用
收藏
页码:87 / 92
页数:6
相关论文
共 10 条
[1]  
Barth TFW, 1932, Z KRISTALLOGR, V81, P376
[2]   QUANTITATIVE PHASE-ANALYSIS USING THE RIETVELD METHOD [J].
BISH, DL ;
HOWARD, SA .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1988, 21 (02) :86-91
[3]  
Brindley G. W., 1945, PHILOS MAG, V36, P347, DOI DOI 10.1080/14786444508520918
[4]   CHOICE OF COLLIMATORS FOR A CRYSTAL SPECTROMETER FOR NEUTRON DIFFRACTION [J].
CAGLIOTI, G ;
PAOLETTI, A ;
RICCI, FP .
NUCLEAR INSTRUMENTS & METHODS, 1958, 3 (04) :223-228
[5]  
Jordan B., 1990, POWDER DIFFR, V5, P64, DOI 10.1017/S0885715600015359
[6]   MODELING THE SILICA GLASS STRUCTURE BY THE RIETVELD METHOD [J].
LEBAIL, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 183 (1-2) :39-42
[7]   SIMULTANEOUS STRUCTURE AND SIZE-STRAIN REFINEMENT BY THE RIETVELD METHOD [J].
LUTTEROTTI, L ;
SCARDI, P .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1990, 23 :246-252
[8]  
LUTTEROTTI L, 1996, UNPUB
[9]  
OConnor B. H., 1988, POWDER DIFFR, V3, P2, DOI [10.1017/S0885715600013026, DOI 10.1017/S0885715600013026]
[10]   ABSORPTION CONTRAST EFFECTS IN THE QUANTITATIVE XRD ANALYSIS OF POWDERS BY FULL MULTIPHASE PROFILE REFINEMENT [J].
TAYLOR, JC ;
MATULIS, CE .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1991, 24 :14-17