Water Splitting by Tungsten Oxide Prepared by Atomic Layer Deposition and Decorated with an Oxygen-Evolving Catalyst

被引：279

作者：

Liu, Rui ^{[2
]}

Lin, Yongjing ^{[2
]}

Chou, Lien-Yang ^{[1
]}

Sheehan, Stafford W. ^{[2
]}

He, Wangshu ^{[1
]}

Zhang, Fan ^{[1
]}

Hou, Harvey J. M. ^{[1
]}

Wang, Dunwei ^{[2
]}

机构：

[1] Univ Massachusetts Dartmouth, Dept Chem & Biochem, N Dartmouth, MA 02747 USA

[2] Boston Coll, Dept Chem, Merkert Chem Ctr, Chestnut Hill, MA 02467 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 02期

基金：

美国国家科学基金会;

关键词：

electrochemistry; nanostructures; photochemistry; solar energy; water splitting; PHOTOSYSTEM-II; SOLAR-ENERGY; FILMS; PHOTOELECTROCHEMISTRY; OXIDATION; ELECTRODE; HYDROGEN; COMPLEX; PLANET; WO3;

D O I：

10.1002/anie.201004801

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heteronanostructured photoelectrodes were fabricated by atomic layer deposition of WO3 and stabilized with an Mn-based oxygen-evolving catalyst. The resulting electrode absorbs photons to create electrons and holes, the separation of which is assisted by the built-in field within the semiconductor. Electrons are collected, and holes transferred to the catalyst to split H2O into oxygen and hydrogen (see schematic). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：499 / 502

页数：4

共 28 条

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