Two-dimensional sheets of rugged hexagonal grids of [Cu6(trans-oxen)3(μ3-OH)2(H2O)2]n4n+ with copper(II) bridged by trans-oxamidate (oxen) and μ3-OH- groups

被引：25

作者：

Chen, ZN ^{[1
]}

Zhang, HX

Su, CY

Zhou, ZY

Zheng, KC

Kang, BS

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Sichuan, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 15期

关键词：

D O I：

10.1021/ic9714246

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination polymeric cation of [Cu-6(trans-oxen)(3)(mu(3)-OH)(2)(H2O)(2)](n)Br-4n . 3nH(2)O exhibits a two-dimensional sheetlike framework with rugged hexagonal grids of copper(II) ions bridged by alternating trans-oxamidate and mu(3)-OH- groups producing antiferromagnetic interactions; The polymeric cation, anions Br-, and H2O molecules coordinated and solvated are connected to one another via a variety of H-bonded linkages to produce a three-dimensional extended network.

引用

页码：3877 / +

页数：5

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