Isotopes of volatile organic compounds: An emerging approach for studying atmospheric budgets and chemistry

被引:77
作者
Goldstein, AH [1 ]
Shaw, SL [1 ]
机构
[1] Univ Calif Berkeley, Dept Environm Sci Policy & Management, Berkeley, CA 94720 USA
关键词
D O I
10.1021/cr0206566
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A review on the use of isotopes to study gas-phase atmospheric volatile organic compounds (VOC) was presented. A summary of recent measurement and theoretical advances in the use of stable isotopes to study field measurements of atmospheric VOCs isotopic composition, was provided. It was observed that all of the published measurements for isotopic composition of atmospheric VOCs were focused on the C isotopes. Given the capabilities of commercially available instrumentation for also measuring H, N, or O in continuous-flow mode, there could be an opportunity for further development in the measurement of isotopes for other elements in VOCs.
引用
收藏
页码:5025 / 5048
页数:24
相关论文
共 136 条
[1]   Natural abundance carbon isotope composition of isoprene reflects incomplete coupling between isoprene synthesis and photosynthetic carbon flow [J].
Affek, HP ;
Yakir, D .
PLANT PHYSIOLOGY, 2003, 131 (04) :1727-1736
[2]   Method for measuring carbon kinetic isotope effects of gas-phase reactions of light hydrocarbons with the hydroxyl radical [J].
Anderson, RS ;
Czuba, E ;
Ernst, D ;
Huang, L ;
Thompson, AE ;
Rudolph, J .
JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (32) :6191-6199
[3]  
ANDERSON RS, 2002, JOINT INT S ATM CHEM
[4]   Methyl halide emissions from savanna fires in southern Africa [J].
Andreae, MO ;
Atlas, E ;
Harris, GW ;
Helas, G ;
deKock, A ;
Koppmann, R ;
Maenhaut, W ;
Mano, S ;
Pollock, WH ;
Rudolph, J ;
Scharffe, D ;
Schebeske, G ;
Welling, M .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1996, 101 (D19) :23603-23613
[5]   GAS-CHROMATOGRAPHY - STABLE ISOTOPE RATIO ANALYSIS AT NATURAL ABUNDANCE LEVELS [J].
BARRIE, A ;
BRICOUT, J ;
KOZIET, J .
BIOMEDICAL MASS SPECTROMETRY, 1984, 11 (11) :583-588
[6]   THE ANALYSIS OF THE C1-C5 COMPONENTS OF NATURAL-GAS SAMPLES USING GAS-CHROMATOGRAPHY COMBUSTION ISOTOPE RATIO MASS-SPECTROMETRY [J].
BAYLIS, SA ;
HALL, K ;
JUMEAU, EJ .
ORGANIC GEOCHEMISTRY, 1994, 21 (6-7) :777-785
[7]   Measurements of the carbon and hydrogen isotopes of atmospheric methane at Izana, Tenerife:: Seasonal cycles and synoptic-scale variations [J].
Bergamaschi, P ;
Bräunlich, M ;
Marik, T ;
Brenninkmeijer, CAM .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2000, 105 (D11) :14531-14546
[8]   MATURITY RELATED MIXING MODEL FOR METHANE, ETHANE AND PROPANE, BASED ON CARBON ISOTOPES [J].
BERNER, U ;
FABER, E .
ORGANIC GEOCHEMISTRY, 1988, 13 (1-3) :67-72
[9]   Carbon isotope ratios of methyl bromide and methyl chloride emitted from a coastal salt marsh [J].
Bill, M ;
Rhew, RC ;
Weiss, RF ;
Goldstein, AH .
GEOPHYSICAL RESEARCH LETTERS, 2002, 29 (04) :4-1
[10]   Carbon isotope fractionation of methyl bromide during agricultural soil fumigations [J].
Bill, M ;
Miller, LG ;
Goldstein, AH .
BIOGEOCHEMISTRY, 2002, 60 (02) :181-190