Preparation and reactivity of poly [N-(arylmethyl)phenazasiline]s.: Effects of substituent on the N atom on poly(phenazasiline)

被引:13
作者
Nakao, H
Hayashi, H
Okita, K
机构
[1] Japan Chem Innovat Inst, Res & Dev Div, Chiyoda Ku, Tokyo 1010051, Japan
[2] Japan Chem Innovat Inst, Adv Mat Lab, Tsukuba, Ibaraki 3050047, Japan
关键词
poly(phenazasiline); reduction; effect of the substituent;
D O I
10.1295/polymj.33.498
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The preparation of phenazasiline-containing π-conjugated polymers by reductive coupling of 2, 8-dibromophenazasiline was presented. The infrared spectra of the polymer was measured to investigate the molecular structure. An interesting electrphoresim and high efficiency as hole transporting polymeric material was observed by the resulting polymers. X-ray analysis of the monomers showed that the substituent on the Si atom did not change ultraviolet λmax of the polymers.
引用
收藏
页码:498 / 501
页数:4
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