Self-cleaning cotton by porphyrin-sensitized visible-light photocatalysis

被引:53
作者
Afzal, Shabana [1 ]
Daoud, Walid A. [1 ]
Langford, Steven J. [2 ]
机构
[1] Monash Univ, Sch Appl Sci & Engn, Churchill, Vic 3842, Australia
[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
关键词
TITANIA FILMS; ANATASE TIO2; DEGRADATION; COMPLEXES; OXIDATION; METAL; WATER; FORMALDEHYDE; PERFORMANCE; TEXTILES;
D O I
10.1039/c2jm15146d
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Self-assembled monolayers of meso-tetra(4-carboxyphenyl) porphyrin (TCPP) were formed on anatase coated-cotton fabric to confer visible-light sensitized self-cleaning properties. A complete degradation of methylene blue in 110 min and removal of coffee and red wine stains in 16 h indicate that TiO2/TCPP-coated cotton fabrics exhibit superior visible-light self-cleaning performance as compared to bare TiO2-coated cotton. The fabrics were characterized by UV-Vis, FESEM, XRD and fluorescence spectroscopy. Visible-light induced self-cleaning cotton offers a great potential for indoor self-cleaning applications.
引用
收藏
页码:4083 / 4088
页数:6
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