Synthesis of carba-sugars from (-)-quinic acid

被引：9

作者：

Carballido, M ^{[1
]}

Castedo, L ^{[1
]}

González, C ^{[1
]}

机构：

[1] Univ Santiago Compostela, Fac Quim, Dept Quim Organ & Unidad Asciada, CSIC, Santiago 15706, Spain

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(01)00601-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(1S,2R,3R,4S,5R)- (3a) and (1S,2S,3S,4S,5R)-1,2,3,4,5-pentahydroxy-1-hydroxymethylcyclohexane (4a), (1R,2R,3R, 4S,5R)- (3b) and (1R,2S,3S,4S,5R)-1,2,3,4,5-pentahydroxycyclohexan-1-carboxylic acid (4b) are reported. The syntheses exploit the diastereoselective oxidation of the 5,6-double bond of the quinic acid-derived lactone 2 with osmium tetroxide. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：3973 / 3976

页数：4

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