Amine-terminal polystyrenes: A new strategy for synthesis and new methods for determination of functionality

被引:41
作者
Cernohous, JJ
Macosko, CW [1 ]
Hoye, TR
机构
[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA
[2] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA
关键词
D O I
10.1021/ma971142p
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Polymers bearing a single alkyl chloride at the chain end were synthesized using anionic polymerization techniques. Specifically, living polystyrene (PS) anions were treated with commercially available (4-chlorobutyl)dimethylchlorosilane and found to react chemoselectively at the electrophilic silicon atom.(1) The pendant alkyl chloride on these PS chains was subsequently transformed into alkyl azide and aliphatic amine functionalities. The gel permeation chromatograms for the synthesized polymers were found to have relatively narrow molecular weight distributions (M-w/M-n < 1.09) after the end-capping reaction. Nuclear magnetic resonance (NMR) spectroscopy and gel permeation chromatography (GPC) studies were used to quantify the degree of functionalization.
引用
收藏
页码:3759 / 3763
页数:5
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