Nitric acid trihydrate (NAT) in polar stratospheric clouds

被引:169
作者
Voigt, C
Schreiner, J
Kohlmann, A
Zink, P
Mauersberger, K
Larsen, N
Deshler, T
Kröger, C
Rosen, J
Adriani, A
Cairo, F
Di Donfrancesco, G
Viterbini, M
Ovarlez, J
Ovarlez, H
David, C
Dörnbrack, A
机构
[1] Max Planck Inst Kernphys, Div Atmospher Phys, D-69029 Heidelberg, Germany
[2] Danish Meteorol Inst, Div Middle Atmosphere Res, DK-2100 Copenhagen, Denmark
[3] Univ Wyoming, Dept Atmospher Sci, Laramie, WY 82071 USA
[4] CNR, Ist Fis Atmosfera, I-00133 Rome, Italy
[5] Ecole Polytech, CNRS, Meteorol Dynam Lab, F-91128 Palaiseau, France
[6] Univ Paris, Inst Pierre Simon Laplace, CNRS, Serv Aeron, F-75252 Paris, France
[7] DLR Oberpfaffenhofen, Inst Phys Atmosphare, D-82234 Wessling, Germany
关键词
D O I
10.1126/science.290.5497.1756
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
A comprehensive investigation of polar stratospheric clouds was performed on 25 January 2000 with instruments onboard a balloon gondola flown from Kiruna, Sweden. Cloud layers were repeatedly encountered at altitudes between 20 and 24 kilometers over a wide range of atmospheric temperatures (185 to 197 kelvin). Particle composition analysis showed that a large fraction of the cloud layers was composed of nitric acid trihydrate (NAT) particles, containing water and nitric acid at a molar ratio of 3:1; this confirmed that these long-sought solid crystals exist well above ice formation temperatures. The presence of NAT particles enhances the potential for chlorine activation with subsequent ozone destruction in polar regions, particularly in early and late winter.
引用
收藏
页码:1756 / 1758
页数:3
相关论文
共 29 条
[1]  
ADRIANI A, 1998, P 18 QUADR OZ S AQ 1, V2, P879
[2]   MULTIWAVELENGTH LIDAR MEASUREMENTS OF STRATOSPHERIC AEROSOLS ABOVE SPITSBERGEN DURING WINTER 1992 93 [J].
BEYERLE, G ;
NEUBER, R ;
SCHREMS, O ;
WITTROCK, F ;
KNUDSEN, B .
GEOPHYSICAL RESEARCH LETTERS, 1994, 21 (01) :57-60
[3]   Particle microphysics and chemistry in remotely observed mountain polar stratospheric clouds [J].
Carslaw, KS ;
Wirth, M ;
Tsias, A ;
Luo, BP ;
Dornbrack, A ;
Leutbecher, M ;
Volkert, H ;
Renger, W ;
Bacmeister, JT ;
Peter, T .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1998, 103 (D5) :5785-5796
[4]   Increased stratospheric ozone depletion due to mountain-induced atmospheric waves [J].
Carslaw, KS ;
Wirth, M ;
Tsias, A ;
Luo, BP ;
Drnbrack, A ;
Leutbecher, M ;
Volkert, H ;
Renger, W ;
Bacmeister, JT ;
Reimer, E ;
Peter, T .
NATURE, 1998, 391 (6668) :675-678
[5]   STRATOSPHERIC AEROSOL GROWTH AND HNO3 GAS-PHASE DEPLETION FROM COUPLED HNO3 AND WATER-UPTAKE BY LIQUID PARTICLES [J].
CARSLAW, KS ;
LUO, BP ;
CLEGG, SL ;
PETER, T ;
BRIMBLECOMBE, P ;
CRUTZEN, PJ .
GEOPHYSICAL RESEARCH LETTERS, 1994, 21 (23) :2479-2482
[6]   NITRIC-ACID CLOUD FORMATION IN THE COLD ANTARCTIC STRATOSPHERE - A MAJOR CAUSE FOR THE SPRINGTIME OZONE HOLE [J].
CRUTZEN, PJ ;
ARNOLD, F .
NATURE, 1986, 324 (6098) :651-655
[7]   Vertical profiles of volcanic aerosol and polar stratospheric clouds above Kiruna, Sweden: Winters 1993 and 1995 [J].
Deshler, T ;
Oltmans, SJ .
JOURNAL OF ATMOSPHERIC CHEMISTRY, 1998, 30 (01) :11-23
[8]   Determining the index of refraction of polar stratospheric clouds above Andoya (69°N) by combining size-resolved concentration and optical scattering measurements [J].
Deshler, T ;
Nardi, B ;
Adriani, A ;
Cairo, F ;
Hansen, G ;
Fierli, F ;
Hauchecorne, A ;
Pulvirenti, L .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 2000, 105 (D3) :3943-3953
[9]   Mountain-wave-induced record low stratospheric temperatures above northern Scandinavia [J].
Dörnbrack, A ;
Leutbecher, M ;
Kivi, R ;
Kyrö, E .
TELLUS SERIES A-DYNAMIC METEOROLOGY AND OCEANOGRAPHY, 1999, 51 (05) :951-963
[10]   INSITU MEASUREMENTS OF TOTAL REACTIVE NITROGEN, TOTAL WATER, AND AEROSOL IN A POLAR STRATOSPHERIC CLOUD IN THE ANTARCTIC [J].
FAHEY, DW ;
KELLY, KK ;
FERRY, GV ;
POOLE, LR ;
WILSON, JC ;
MURPHY, DM ;
LOEWENSTEIN, M ;
CHAN, KR .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1989, 94 (D9) :11299-11315