Carbon-carbon bond formation through double Sp2 C-H activations:: Synthesis of ferrocenyl oxazoline derivatives

被引：164

作者：

Xia, Ji-Bao ^{[1
]}

You, Shu-Li ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organmet Chem, Shanghai 200032, Peoples R China

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 20期

关键词：

D O I：

10.1021/om700806e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Direct arylation of simple arenes with ferrocenyl oxazolines was achieved in the presence of a stoichiometric amount of Pd(OAC)(2) or a catalytic amount of palladium with excess oxidant such as Cu(OAC)(2). This double sp(2) C-H activation process provides a unique access to the aryl-substituted ferrocene derivatives, even in the enantiopure form of planar chirality, in a few steps from readily available starting materials.

引用

页码：4869 / 4871

页数：3

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