Nanoparticle self-assembly of hierarchically ordered microcapsule structures

被引:136
作者
Rana, RK
Murthy, VS
Yu, J
Wong, MS
机构
[1] Rice Univ, Dept Chem & Biomol Engn, Houston, TX 77251 USA
[2] Rice Univ, Dept Chem, Houston, TX 77251 USA
关键词
D O I
10.1002/adma.200401612
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Microcapsules with multilayer-thick shells are synthesized by depositing negatively charged nanoparticles around cationic polyamine aggregates crosslinked by multivalent counteranions (see Figure and inside cover). Unique among hollow-sphere preparative routes, this rapid and green synthesis leads to a robust organic/inorganic hybrid structure, applies to a wide spectrum of colloidal species, and permits the non-destructive encapsulation of water-soluble compounds.
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页码:1145 / +
页数:7
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