Hydrodehalogenation of 2,4-dibromophenol by electrochemical reduction

被引：14

作者：

Cheng, H

Scott, K ^{[1
]}

Christensen, PA

机构：

[1] Newcastle Univ, Sch Chem Engn & Adv Mat, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] Newcastle Univ, Sch Nat Sci, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2003年 / 33卷 / 10期

关键词：

2,4-dibromophenol (DBP); electrochemical reduction; hydrodehalogenation (HDH); solid polymer electrolyte cells;

D O I：

10.1023/A:1025863711665

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical hydrodehalogenation (HDH) of 2,4-dibromophenol (DBP) has been carried out by electrochemical reduction in H-cells and solid polymer electrolyte (SPE) cells using catalysed cathodes. The electrochemical process gave high conversions of up to 95%, high selectivities of up to 98%, high current efficiencies of up to 98.5% and energy consumption as low as 2.2 kW h ( kg DBP)(-1). The type of the catalyst plays a decisive role in the efficiency of the HDH of DBP, with palladium being an attractive material. The effect of current density, DBP concentration, supporting electrolyte and temperature, on the HDH is reported.

引用

页码：893 / 899

页数：7

共 23 条

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