A stable η2-bonded diazoalkane complex

被引：33

作者：

Schaub, Thomas ^{[1
]}

Radius, Udo ^{[1
]}

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 13-14期

关键词：

nickel; NHC complexes; diazoalkane complexes; olefine complexes;

D O I：

10.1002/zaac.200700203

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterization of the new complexes [Ni(iPr(2)Im)(2)(eta(2)-C,C-Me2C=CHCOMe)] (2), [Ni(iPr(2)Im)(2) (eta(2)-H2C=CH-(4-C5H4N)] (3) and [Ni(iPr(2)Im)(2)(eta(2)- N,N'-N2CPh2)] (4) is reported. Complex 4 is remarkably stable under an inert gas atmosphere and does not undergo nitrogen loss under thermal or photochemical conditions.

引用

页码：2168 / 2172

页数：5

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