Strong enhancement of second-harmonic generation (SHG) response through multi-chiral centers and metal-coordination

被引：57

作者：

Ye, Q ^{[1
]}

Tang, YZ ^{[1
]}

Wang, XS ^{[1
]}

Xiong, RG ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

来源：

DALTON TRANSACTIONS | 2005年 / 09期

关键词：

D O I：

10.1039/b503039k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of CdCl2 with L (L = trans- 2,3-dihydro-2-(4 '-pyridyl)-3-(3 ''-cyanophenyl)benzo[ e] indole) in the presence of NaN3 and water offers a novel route to [Cd(L-N-3)(2)(H2O)(2)](n) (1), a 1D infinite molecular box with approximate dimensions 10.37 x 6.64 e; 1 is shown to display a very strong SHG response that is 80 times that observed for urea.

引用

页码：1570 / 1573

页数：4

共 50 条

[1]

Agullo-Lopez F., 1994, Electrooptics phenomena, materials and applications

[2] Helical and network coordination polymers based on a novel C2-symmetric ligand :: SHG enhancement through specific metal coordination [J].

Anthony, SP ;

Radhakrishnan, TP .

CHEMICAL COMMUNICATIONS, 2004, (09) :1058-1059

[3] Non-centrosymmetric racemates:: space-group frequencies and conformational similarities between crystallographically independent molecules [J].

Dalhus, B ;

Görbitz, CH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2000, 56 :715-719

[4] An intramolecular [2+3] cycloaddition route to fused 5-heterosubstituted tetrazoles [J].

Demko, ZP ;

Sharpless, KB .

ORGANIC LETTERS, 2001, 3 (25) :4091-4094

[5] Preparation of 5-substituted 1H-tetrazoles from nitriles in water [J].

Demko, ZP ;

Sharpless, KB .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (24) :7945-7950

[6]

Desiraju G. R., 1989, DESIGN ORGANIC SOLID

[7] Second-order nonlinear optical properties of transition metal complexes [J].

Di Bella, S .

CHEMICAL SOCIETY REVIEWS, 2001, 30 (06) :355-366

[8] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

[9] STRUCTURAL STUDIES OF TRIGLYCINE SULFATE .2. AFTER X-IRRADIATION-FIELD TREATMENT (STRUCTURE-B) [J].

FLETCHER, SR ;

KEVE, ET ;

SKAPSKI, AC .

FERROELECTRICS, 1976, 14 (3-4) :789-799

[10] Noncentrosymmetric oxides [J].

Halasyamani, PS ;

Poeppelmeier, KR .

CHEMISTRY OF MATERIALS, 1998, 10 (10) :2753-2769

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