Characterization of copper corrosion products originated in simulated uterine fluids and on packaged intrauterine devices

被引:46
作者
Bastidas, JM [1 ]
Mora, N [1 ]
Cano, E [1 ]
Polo, JL [1 ]
机构
[1] CSIC, Ctr Nacl Invest Met, Madrid 28040, Spain
关键词
Uterine fluids;
D O I
10.1023/A:1011288701499
中图分类号
R318 [生物医学工程];
学科分类号
0831 ;
摘要
This paper studies the characterization of corrosion products originated after 1 and 12 weeks' immersion of copper specimens in simulated uterine fluids at pH 6.3 and 8.0 and at 37 degreesC temperature. The experimental techniques used were X-ray photo-electron spectroscopy, scanning electron microscopy, and energy dispersive X-ray. The compounds found were calcite (CaCO3), calcium phosphate, cuprite (Cu2O) and copper hydroxide (Cu(OH)(2)). The morphology of corrosion products was a non-uniform, layer showing some paths through which copper ions can be released. In parallel, corrosion products formed on packaged, unused copper-containing intrauterine devices (IUD) were analyzed. Cuprite (Cu2O) and chalcocite (Cu2S) were the main species identified. (C) 2001 Kluwer Academic Publishers.
引用
收藏
页码:391 / 397
页数:7
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