Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct

被引：57

作者：

Azhakar, Ramachandran ^{[1
]}

Tavcar, Gasper ^{[1
]}

Roesky, Herbert W. ^{[1
]}

Hey, Jakob ^{[1
]}

Stalke, Dietmar ^{[1
]}

机构：

[1] Univ Gottingen, Inst Anorgan Chem, D-37077 Gottingen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2011年 / 04期

关键词：

Silylenes; Boranes; Lewis acid adducts; N-HETEROCYCLIC CARBENES; STABLE SILYLENE; COMPLEXES; METAL; REACTIVITY; ALKENES; CHEMISTRY; LIGAND; BOND; DICHLOROSILYLENE;

D O I：

10.1002/ejic.201001188

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first stable chlorosilylene-BH3 adduct was synthesized in the reaction of N-heterocyclic carbene (NHC) stabilized dichlorosilylene either with equivalent amounts of LiBH4 or with equivalent amounts of a BH3 center dot THF solution. The chlorosilylene-BH3 adduct was characterized by single-crystal X-ray structural analysis, NMR and IR spectroscopy, EI mass spectrometry, and elemental analysis.

引用

页码：475 / 477

页数：3

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