1,2-benzothiaborolide: A new heteroaromatic analogue of indenyl

被引：11

作者：

Ashe, AJ ^{[1
]}

Kampf, JW ^{[1
]}

Schiesher, M ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 23期

关键词：

D O I：

10.1021/om000650b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2-methylbenzenethiol with 2 equiv of BuLi followed by, (i-Pr)(2)NBCl(2) affords 2,3-dihydro-2-(diisopropylamino)-1,2-benzothiaborole (10), which can be deprotonated by t-BuLi to form lithium 2-(diisopropylamino)-1,2-benzothiaborolide (3). The benzothiaborolide was converted to the Cp*ZrCl(2) complex II and the Cp*Ru complex. 12, in which the thiaborolide ring is eta (5)-coordinated to Ru.

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页码：4681 / 4683

页数：3

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