PEG-catalytic water splitting in the interface of a bipolar membrane

被引：66

作者：

Fu, RQ ^{[1
]}

Xu, TW ^{[1
]}

Wang, G ^{[1
]}

Yang, WH ^{[1
]}

Pan, ZX ^{[1
]}

机构：

[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2003年 / 263卷 / 02期

关键词：

bipolar membrane; water splitting; interface; polyethylene glycol; CITRIC-ACID PRODUCTION; EXCHANGE MEMBRANES; ION-TRANSPORT; ELECTRODIALYSIS; DISSOCIATION; PERFORMANCE; STATE;

D O I：

10.1016/S0021-9797(03)00307-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This paper investigates the effect of polyethylene glycol (PEG) on the water dissociation of bipolar membranes. To do this, bipolar membranes were prepared by immersing anion exchange membranes in different-concentration solutions of different-molecular-weight PEGs and then casting the solutions of sulfonated polyphenylene oxide (SPPO) on the anion exchange membranes. All the bipolar membranes with PEG in the interface are evaluated by current-voltage curves. The experimental results prove that PEG has excellent catalytic function for water dissociation. Furthermore, this function is enhanced by both PEG amount (PEG concentration) and PEG molecular weight in the interface of a bipolar membrane. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：386 / 390

页数：5

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