Synthetic disproof against the structure proposed for alectrol, the germination stimulant from Vigna unguiculata

被引：22

作者：

Mori, K

Matsui, J

Bando, M

Kido, M

Takeuchi, Y

机构：

[1] Sci Univ Tokyo, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan

[2] Otsuka Pharmaceut Co Ltd, Tokushima 7710130, Japan

[3] Utsunomiya Univ, Weed Sci Ctr, Utsunomiya, Tochigi 3210943, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 33期

关键词：

biologically active compound; lactones; NMR; X-Ray crystal structure;

D O I：

10.1016/S0040-4039(98)01238-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several compounds [(+/-)-3a, (+/-)-3b, (+/-)-10, (+/-)-11 and (+/-)-12] with the structures related to that (3) proposed for alectrol, the germination stimulant, were synthesized. The structure (+/-)-3a was solved by X-ray crystallographic analysis. Comparison of the H-1 NMR data of the synthetic compounds with those reported for alectrol disproved the correctness of the proposed structure 3. (C) 1998 Elsevier Science Ltd. All rights reserved.

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页码：6023 / 6026

页数：4

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