Immobilization and chelation of metal complexes with bifunctional phosphine ligands: A solid-state NMR study

被引：31

作者：

Behringer, KD ^{[1
]}

Blumel, J ^{[1
]}

机构：

[1] TECH UNIV MUNICH, INST ANORGAN CHEM, D-85747 GARCHING, GERMANY

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 05期

关键词：

D O I：

10.1039/cc9960000653

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Si-29 CP MAS NMR shows that a transition-metal complex with two bifunctional phosphine ligands such as (CO)(2)Ni[PPh(2)(C6H4)SiMe(2)OEt](2), when attached to a silica surface according to a commonly used procedure, is mainly anchored by just one ligand.

引用

页码：653 / 654

页数：2

共 23 条

[1] CHARACTERIZATION OF CHEMICALLY MODIFIED SILICA-GELS BY SI-29 AND C-13 CROSS-POLARIZATION AND MAGIC ANGLE SPINNING NUCLEAR MAGNETIC-RESONANCE
BAYER, E
ALBERT, K
REINERS, J
NIEDER, M
MULLER, D
[J]. JOURNAL OF CHROMATOGRAPHY, 1983, 264 (02): : 197 - 213
[2] SUSPENSION NMR-SPECTROSCOPY OF PHOSPHINES AND CARBONYLNICKEL COMPLEXES IMMOBILIZED ON SILICA
BEHRINGER, KD
BLUMEL, J
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (11): : 1723 - 1728
[3] NI-61 NMR-SPECTROSCOPY OF DICARBONYLNICKEL AND TRICARBONYLNICKEL COMPLEXES
BEHRINGER, KD
BLUMEL, J
[J]. MAGNETIC RESONANCE IN CHEMISTRY, 1995, 33 (09) : 729 - 733
[4] BEHRINGER KD, IN PRESS INORG CHEM
[5] STUDIES OF PHOSPHORUS(III) LIGANDS AND THEIR COMPLEXES OF NI(II), PD(II), AND PT(II) IMMOBILIZED ON INSOLUBLE SUPPORTS BY HIGH-RESOLUTION SOLID-STATE P-31 NMR USING MAGIC-ANGLE SPINNING TECHNIQUES
BEMI, L
CLARK, HC
DAVIES, JA
FYFE, CA
WASYLISHEN, RE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (02) : 438 - 445
[6] BLUMEL J, 1995, J AM CHEM SOC, V117, P2112
[7] BLUMEL J, 1994, INORG CHEM, V33, P5050
[8] Engelhardt G., 1987, HIGH RESOLUTION SOLI
[9] FYFE CA, 1994, NMR TECHNIQUES CATAL
[10] REVERSED-PHASE CHROMATOGRAPHIC AND NUCLEAR-MAGNETIC-RESONANCE STUDIES OF BIDENTATE ALKYLSILANE-MODIFIED SILICA
GILPIN, RK
GANGODA, ME
[J]. JOURNAL OF CHROMATOGRAPHIC SCIENCE, 1990, 28 (06) : 277 - 281

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