Solid state coordination chemistry of the copper cyanide organoamine system:: hydrothermal syntheses and structural characterization of [(Cu2(bpy)2(CN)}Cu5(CN)6] and [Cu4(CN)4(biquin)]

被引:95
作者
Chesnut, DJ [1 ]
Zubieta, J [1 ]
机构
[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA
关键词
D O I
10.1039/a802641f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The hydrothermal reactions of CuCN and Cu(NO3)(2).2.5H(2)O with the appropriate organonitrogen ligand in water yielded a one-dimensional chain, [Cu-4(CN)(4)(biquin)] 1, and a material with a two-dimensional anionic honeycomb network and interpenetrating binuclear cations, [{Cu-2-(bpy)(2)(CN)}Cu-5(CN)(6)] 2.
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页码:1707 / 1708
页数:2
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