Mechanism and potential energy surface for photoisomerization of stilbene in zeolite nanospace

被引：7

作者：

Kuriyama, Y ^{[1
]}

Takeya, H

Oishi, S

Kojima, M

机构：

[1] Kitasato Univ, Sch Sci, Dept Chem, Kanagawa 2288555, Japan

[2] Cosmo Res Inst, Satte, Saitama 3400193, Japan

[3] Shinshu Univ, Fac Agr, Dept Biosci & Biotechnol, Nagano 3900802, Japan

来源：

CHEMISTRY LETTERS | 1998年 / 08期

关键词：

D O I：

10.1246/cl.1998.843

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The photoisomerization of cis- and trans-stilbenes adsorbed in zeolite supercage was studied by means of Raman spectroscopy for in situ analysis of the isomer ratio in the photostationary state. It was found that the isomerization proceeds mainly through the singlet excited states for NaY and triplet excited states for KY, and also a new potential energy surface for the photoisomerization was proposed.

引用

页码：843 / 844

页数：2

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