Synthesis of a D3-symmetric "trefoil" knotted cyclophane

被引：30

作者：

Arias, Karla I. ^{[1
]}

Zysman-Colman, Eli ^{[2
]}

Loren, Jon C. ^{[3
]}

Linden, Anthony ^{[1
]}

Siegel, Jay S. ^{[1
]}

机构：

[1] Univ Zurich, Inst Organ Chem, CH-8057 Zurich, Switzerland

[2] Univ Sherbrooke, Fac Sci, Sherbrooke, PQ J1K 2R1, Canada

[3] Genom Inst Novartis Res, Dept Med Chem, San Diego, CA 92121 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 34期

关键词：

SINGLE-STRANDED-DNA; MOLECULAR KNOTS; ABSOLUTE-CONFIGURATION; PROTEIN; PALLADIUM; COPPER(I); STEREOCHEMISTRY; RECOMBINATION; DERIVATIVES; PRECURSOR;

D O I：

10.1039/c1cc11209k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A D-3-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D-3-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.

引用

页码：9588 / 9590

页数：3

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