Silicon electronic effect in the Pauson-Khand reaction of alkynylsilanes with allenes

被引：22

作者：

Antras, F ^{[1
]}

Ahmar, M ^{[1
]}

Cazes, B ^{[1
]}

机构：

[1] Univ Lyon 1, CNRS, Lab Chim Organ 1, F-69622 Villeurbanne, France

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 46期

关键词：

Pauson Khand reaction; allene; alkynylsilane; cobalt; electronic effect;

D O I：

10.1016/S0040-4039(01)01750-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The beta -effect of silicon was shown to be a determining factor for the regioselectivity of the Pauson-Khand reaction of alkynylsilanes with allenes. This electronic effect accounts for the formation of 3-trimethylsilyl-4-alkylidenecyclopentenones observed from monosubstituted allenes. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：8157 / 8160

页数：4

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