Exploiting Cavities in Supramolecular Gels

被引:141
作者
Foster, Jonathan A. [1 ]
Steed, Jonathan W. [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
基金
英国工程与自然科学研究理事会;
关键词
calixarenes; cavitands; gels; host-guest systems; supramolecular chemistry; ORGANIC LIQUIDS; CYCLODEXTRIN; GUEST; GELATION; MOLECULES; TEMPLATE; GELATORS; CYCLOTRIVERATRYLENE; ORGANOGELATORS; TRANSITION;
D O I
10.1002/anie.201000070
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Endowing supramolecular gelators with cavities opens up a number of opportunities not possible with other gel systems. The well-established host-guest chemistry of cavitands can be utilized to build up and break down gel structures, introduce responsive functionalities, or enhance selectivity in applications such as catalysis and extraction. Cavity-containing gelators provide an excellent case study for how different aspects of supramolecular chemistry can be used intelligently to create responsive materials. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6718 / 6724
页数:7
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