Synthesis and structure of a 2 Cu-II 2 Cu-I constellation ligated by the new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol

被引：4

作者：

Bhalla, R ^{[1
]}

Helliwell, M ^{[1
]}

Garner, CD ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000921

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new biimidazole, bis(1-methyl-4,5-diphenylimidaz-2-oyl)carbinol, BimOH, is synthesized and employed to form the novel tetrameric constellation [Cu-4(BimOH)(2)(BimO)(2)](4+), involving an (N-im)(2)Cu-II(OR)(2)Cu-II(N-im)(2) centre with a Cu-II...Cu-II separation of 2.998(4) Angstrom and two Cu-I(N-im)(2) moieties ca. 5 Angstrom from the Cu-2 centre, each with an N-Cu-N angle of 169.3(4)degrees.

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页码：921 / 922

页数：2

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