Characterization of planer cathode-supported SOFC prepared by a dual dry pressing method

被引:29
作者
Chen, Gang [1 ]
You, Hong-Xin [2 ]
Kasai, Yutaka [3 ]
Sato, Hiroyuki [1 ]
Abudula, Abuliti [1 ,4 ]
机构
[1] Hirosaki Univ, Fac Sci & Technol, Hirosaki, Aomori 0368560, Japan
[2] Dalian Univ Technol, Chem Engn Coll, Dalian 116024, Peoples R China
[3] Aomori Prefectural Ind Technol Res Ctr, Ind Res Inst, Aomori 0300113, Japan
[4] Hirosaki Univ, NJRISE, Aomori 0300813, Japan
关键词
Solid oxide fuel cell; Cathode-supported; Dry pressing; ScSZ; OXIDE FUEL-CELLS; DIRECT OXIDATION; ANODES; PERFORMANCE; FABRICATION; CO; ELECTROLYTE; METHANE;
D O I
10.1016/j.jallcom.2010.10.218
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cathode-supported solid oxide fuel cells (SOFCs), comprising porous (La0.75Sr0.25)(0.95)MnO3-delta (LSM) + Sm0.2Ce0.8O1.9 (SDC) composite cathode substrate and 11 mol%Sc2O3-doped ZrO2 (ScSZ) electrolyte membranes layer, were successfully fabricated via dual dry pressing method. NiO-SDC anode was prepared by slurry coating method. Phase characterizations and microstructures of electrolyte and cathode were studied by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). No interface reaction took place between LSM/SDC cathode substrate and ScSZ electrolyte layer after sintered at 1300 degrees C. The cell performances were measured at 800 and 750 degrees C, respectively, by changing the external load. The peak power densities were 0.228 and 0.133 W cm(-2), and the corresponding open-circuit voltages of the cell were 1.092 and 1.027V at 800 and 750 degrees C, respectively. Impedance analysis indicated that the performances of the SOFCs were determined essentially by the composition and microstructure of the electrode. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:5159 / 5162
页数:4
相关论文
共 23 条
[1]   Characterization of Cu-CeO2 direct hydrocarbon anodes in a solid oxide fuel cell with lanthanum gallate electrolyte [J].
An, S ;
Lu, C ;
Worrell, WL ;
Gorte, RJ ;
Vohs, JM .
SOLID STATE IONICS, 2004, 175 (1-4) :135-138
[2]   Advanced anodes for high-temperature fuel cells [J].
Atkinson, A ;
Barnett, S ;
Gorte, RJ ;
Irvine, JTS ;
Mcevoy, AJ ;
Mogensen, M ;
Singhal, SC ;
Vohs, J .
NATURE MATERIALS, 2004, 3 (01) :17-27
[3]   Conductivity of SDC and (Li/Na)2CO3 composite electrolytes in reducing and oxidising atmospheres [J].
Boden, Andreas ;
Di, Jing ;
Lagergren, Carina ;
Lindbergh, Gran ;
Wang, Cheng Yang .
JOURNAL OF POWER SOURCES, 2007, 172 (02) :520-529
[4]   The amazing Perovskite anode [J].
Boukamp, BA .
NATURE MATERIALS, 2003, 2 (05) :294-296
[5]   Comparison of the performance of Cu-CeO2-YSZ and Ni-YSZ composite SOFC anodes with H2, CO, and syngas [J].
Costa-Nunes, O ;
Gorte, RJ ;
Vohs, JM .
JOURNAL OF POWER SOURCES, 2005, 141 (02) :241-249
[6]  
Gorte RJ, 2000, ADV MATER, V12, P1465, DOI 10.1002/1521-4095(200010)12:19<1465::AID-ADMA1465>3.0.CO
[7]  
2-9
[8]   A study of thermal stability and methane tolerance of Cu-based SOFC anodes with electrodeposited Co [J].
Gross, Michael D. ;
Vohs, John M. ;
Gorte, Raymond J. .
ELECTROCHIMICA ACTA, 2007, 52 (05) :1951-1957
[9]   Degradation of the electrical conductivity in stabilised zirconia system Part II:: Scandia-stabilised zirconia [J].
Haering, C ;
Roosen, A ;
Schichl, H ;
Schnöller, M .
SOLID STATE IONICS, 2005, 176 (3-4) :261-268
[10]   Anode Supported Solid Oxide Fuel Cells - Deconvolution of Degradation into Cathode and Anode Contributions [J].
Hagen, A. ;
Liu, Y. L. ;
Barfod, R. ;
Hendriksen, P. V. .
SOLID OXIDE FUEL CELLS 10 (SOFC-X), PTS 1 AND 2, 2007, 7 (01) :301-309