In Situ Gelation of Electrolytes for Highly Efficient Gel-State Dye-Sensitized Solar Cells

被引：133

作者：

Chen, Ching-Lun ^{[1
,2
]}

Teng, Hsisheng ^{[1
,2
]}

Lee, Yuh-Lang ^{[1
,2
]}

机构：

[1] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 7010, Taiwan

[2] Natl Cheng Kung Univ, Res Ctr Energy Technol & Strategy, Tainan 7010, Taiwan

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 36期

关键词：

PERFORMANCE;

D O I：

10.1002/adma.201101448

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In Situ Gelation of Electrolytes for Highly Efficient Gel-State Dye-Sensitized Solar Cells By using poly(acrylonitrile-co-vinyl acetate) as a gelator in an acetonitrile-based liquid electrolyte, an in situ gelation of the liquid electrolyte can be performed inside the mesoporous matrix of TiO2 films. By introduction of TiO2 nanoparticles as fillers of the gel-electrolyte, the energy conversion efficiency of a gel-state dye-sensitized solar cell can achieve a value higher than that of a liquid-state cell.

引用

收藏

页码：4199 / +

页数：7

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[1] Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells [J].

Chen, Chia-Yuan ;

Wang, Mingkui ;

Li, Jheng-Ying ;

Pootrakulchote, Nuttapol ;

Alibabaei, Leila ;

Ngoc-le, Cevey-ha ;

Decoppet, Jean-David ;

Tsai, Jia-Hung ;

Graetzel, Carole ;

Wu, Chun-Guey ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

ACS NANO, 2009, 3 (10) :3103-3109

[2] Preparation of highly efficient gel-state dye-sensitized solar cells using polymer gel electrolytes based on poly(acrylonitrile-co-vinyl acetate) [J].

Chen, Ching-Lun ;

Teng, Hsisheng ;

Lee, Yuh-Lang .

JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (03) :628-632

[3] In Situ Low Temperature Polymerization of Bismaleimide for Gel-Type Electrolyte for Dye-Sensitized Solar Cells [J].

Chen, Jian-Ging ;

Chen, Chia-Yuan ;

Wu, Chun-Guey ;

Ho, Kuo-Chuan .

JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (32) :13832-13837

[4] Electron Transport and Recombination in Solid-State Dye Solar Cell with Spiro-OMeTAD as Hole Conductor [J].

Fabregat-Santiago, Francisco ;

Bisquert, Juan ;

Cevey, Le ;

Chen, Peter ;

Wang, Mingkui ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :558-562

[5] Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10% [J].

Ito, Seigo ;

Murakami, Takurou N. ;

Comte, Pascal ;

Liska, Paul ;

Graetzel, Carole ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

THIN SOLID FILMS, 2008, 516 (14) :4613-4619

[6] Supramolecular electrolytes for use in highly efficient dye-sensitized solar cells [J].

Kim, YJ ;

Kim, JH ;

Kang, MS ;

Lee, MJ ;

Won, J ;

Lee, JC ;

Kang, YS .

ADVANCED MATERIALS, 2004, 16 (19) :1753-+

[7] Organic dye-sensitized ionic liquid based solar cells:: Remarkable enhancement in performance through molecular design of indoline sensitizers [J].

Kuang, Daibin ;

Uchida, Satoshi ;

Humphry-Baker, Robin ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (10) :1923-1927

[8] The application of P(MMA-co-MAA)/PEG polyblend gel electrolyte in quasi-solid state dye-sensitized solar cell at higher temperature [J].

Li, Pin Jiang ;

Wu, Ji Huai ;

Huang, Miao Liang ;

Hao, San Cun ;

Lan, Zhang ;

Li, Qinghua ;

Kang, Shijie .

ELECTROCHIMICA ACTA, 2007, 53 (02) :903-908

[9] Photovoltaic performance of dye-sensitized solar cells assembled by in-situ chemical cross-linking [J].

Lim, Su Jung ;

Kang, Yong Soo ;

Kim, Dong-Won .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (08) :1037-1040

[10] An Efficient Organic-Dye-Sensitized Solar Cell with in situ Polymerized Poly(3,4-ethylenedioxythiophene) as a Hole-Transporting Material [J].

Liu, Xizhe ;

Zhang, Wei ;

Uchida, Satoshi ;

Cai, Liping ;

Liu, Bin ;

Ramakrishna, Seeram .

ADVANCED MATERIALS, 2010, 22 (20) :E150-+