Magnetic hollow spheres of periodic mesoporous organosilica and Fe3O4 nanocrystals:: Fabrication and structure control

被引:265
作者
Zhang, Ling [1 ,2 ,3 ]
Qiao, Shizhang [1 ,2 ]
Jin, Yonggang [1 ,2 ]
Chen, Zhigang [1 ,2 ]
Gu, Hongchen [3 ]
Lu, Gao Qing [1 ,2 ]
机构
[1] Univ Queensland, Sch Engn, ARC Ctr Excellence Funct Nanomat, Brisbane, Qld 4072, Australia
[2] Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia
[3] Shanghai Jiao Tong Univ, Inst Micro & Nano Sci & Technol, Shanghai 200030, Peoples R China
关键词
D O I
10.1002/adma.200700900
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Periodic mesoporous organosilica magnetic hollow spheres (PMO-MHS) are synthesized. The particle size, shell wall thickness and saturation magnetization value of PMO-MHS are tunable by varying the ratio of templating agent to magnetic nanoparticles. The high saturation magnetization ensures that these functional mesoporous hollow spheres can be efficient materials for targeted drug delivery assisted by magnetic fields.
引用
收藏
页码:805 / +
页数:6
相关论文
共 22 条
[1]   Development of magnetic nanostructured silica-based materials as potential vectors for drug-delivery applications [J].
Arruebo, M ;
Galán, M ;
Navascués, N ;
Téllez, C ;
Marquina, C ;
Ibarra, MR ;
Santamaría, J .
CHEMISTRY OF MATERIALS, 2006, 18 (07) :1911-1919
[2]   Periodic mesoporous organosilica hollow spheres with tunable wall thickness [J].
Djojoputro, H. ;
Zhou, X. F. ;
Qiao, S. Z. ;
Wang, L. Z. ;
Yu, C. Z. ;
Lu, G. Q. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (19) :6320-6321
[3]   Synthesis of organo-silane functionalized nanocrystal micelles and their self-assembly [J].
Fan, HY ;
Chen, Z ;
Brinker, CJ ;
Clawson, J ;
Alam, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (40) :13746-13747
[4]   Surfactant-assisted synthesis of water-soluble and biocompatible semiconductor quantum dot micelles [J].
Fan, HY ;
Leve, EW ;
Scullin, C ;
Gabaldon, J ;
Tallant, D ;
Bunge, S ;
Boyle, T ;
Wilson, MC ;
Brinker, CJ .
NANO LETTERS, 2005, 5 (04) :645-648
[5]   Self-assembly of ordered, robust, three-dimensional gold nanocrystal/silica arrays [J].
Fan, HY ;
Yang, K ;
Boye, DM ;
Sigmon, T ;
Malloy, KJ ;
Xu, HF ;
López, GP ;
Brinker, CJ .
SCIENCE, 2004, 304 (5670) :567-571
[6]   Stimuli-responsive controlled-release delivery system based on mesoporous silica nanorods capped with magnetic nanoparticles [J].
Giri, S ;
Trewyn, BG ;
Stellmaker, MP ;
Lin, VSY .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (32) :5038-5044
[7]   In vivo magnetic resonance detection of cancer by using multifunctional magnetic nanocrystals [J].
Huh, YM ;
Jun, YW ;
Song, HT ;
Kim, S ;
Choi, JS ;
Lee, JH ;
Yoon, S ;
Kim, KS ;
Shin, JS ;
Suh, JS ;
Cheon, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (35) :12387-12391
[8]   A magnetically separable, highly stable enzyme system based on nanocomposites of enzymes and magnetic nanoparticles shipped in hierarchically ordered, mesocellular, mesoporous silica [J].
Kim, J ;
Lee, J ;
Na, HB ;
Kim, BC ;
Youn, JK ;
Kwak, JH ;
Moon, K ;
Lee, E ;
Kim, J ;
Park, J ;
Dohnalkova, A ;
Park, HG ;
Gu, MB ;
Chang, HN ;
Grate, JW ;
Hyeon, T .
SMALL, 2005, 1 (12) :1203-1207
[9]   Magnetic fluorescent delivery vehicle using uniform mesoporous silica spheres embedded with monodisperse magnetic and semiconductor nanocrystals [J].
Kim, J ;
Lee, JE ;
Lee, J ;
Yu, JH ;
Kim, BC ;
An, K ;
Hwang, Y ;
Shin, CH ;
Park, JG ;
Kim, J ;
Hyeon, T .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (03) :688-689
[10]   Generalized fabrication of multifunctional nanoparticle assemblies on silica spheres [J].
Kim, Jaeyun ;
Lee, Ji Eun ;
Lee, Jinwoo ;
Jang, Youngjin ;
Kim, Sang-Wook ;
an, Kwgjin An ;
Yu, Hing Ho ;
Hyeon, Taeghwan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (29) :4789-4793