MeOH-coordinated Mn12 single-molecule magnet:: structure and magnetic properties of [Mn12O12(OAc)16(MeOH)4]

被引：14

作者：

Bian, GQ ^{[1
]}

Kuroda-Sowa, T ^{[1
]}

Gunjima, N ^{[1
]}

Maekawa, M ^{[1
]}

Munakata, M ^{[1
]}

机构：

[1] Kinki Univ, Fac Sci & Engn, Dept Chem, Osaka 5778502, Japan

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 02期

关键词：

single-molecule magnet; Mn-12; complex; methanol coordination; magnetic properties; crystal structure;

D O I：

10.1016/j.inoche.2004.12.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complex [Mn12O12(OAc)(16)(MeOH)(4)] having MeOH-coordination was synthesized and characterized, whose magnetic behaviors indicate it is a single-molecule magnet with the largest U-eff/k(B) of 76.2 K. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：208 / 211

页数：4

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