New acrylic titanium polymers: 1. Synthesis and characterisation of new titanium trialkoxide methacrylate monomers prepared via the esterification of methacrylic acid by titanium tetraalkoxides

被引：39

作者：

Camail, M

Humbert, M

Margaillan, A

Riondel, A

Vernet, JL

机构：

[1] Univ Toulon & Var, Equipe Accueil Mat & Finalites Specifiques, Lab Chim Appliquee, F-83957 La Garde, France

[2] Soc Elf Atochem, Ctr Rech & Dev Est, Serv Acryliques, F-57501 St Avold, France

来源：

POLYMER | 1998年 / 39卷 / 25期

关键词：

titanium tetraalkoxide; methacrylic acid; monomers;

D O I：

10.1016/S0032-3861(98)00145-1

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In order to obtain a new family of acrylic organotitanium polymers which could be of major interest in the field of non-toxic, self-polishing, antifouling coatings, five acrylic organotitanium monomers, three of which are new, were synthesised. They were analysed by n.m.r. and FTi.r. spectroscopy as well as by microanalysis. Their main features were studied from a structural point of view. The presence of one to three types of structure was shown. The results were linked to the influence of the steric hindrance of the alkoxy groups attached to the titanium atom. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6525 / 6531

页数：7

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