Potassium sensing calix[4]arene crown ethers

被引：23

作者：

Kim, JS ^{[1
]}

Lee, WK

Ra, DY

Lee, YI

Choi, WK

Lee, KW

Oh, WZ

机构：

[1] Konyang Univ, Dept Chem, Nonsan 320711, South Korea

[2] Korea Ginseng & Tobacco Res Inst, Taejon 305345, South Korea

[3] Changwon Natl Univ, Dept Chem, Changwon 641773, South Korea

[4] Korea Atom Energy Res Inst, Taejon 305600, South Korea

来源：

MICROCHEMICAL JOURNAL | 1998年 / 59卷 / 03期

关键词：

D O I：

10.1006/mchj.1998.1630

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

1,3-Alternate calix[4]arene crown-5 (1) and corresponding biscrown-5 (2) were synthesized and the complexation behavior with alkali metal ions examined. For both 1 and 2, potassium ion was selectively extracted from aqueous phase into organic phase over other alkali metal ions based on two phase extraction experiment. The complexation ratio between calix[4]arene biscrown-5 (2)1 in which two crown cavities connect to the calix[4]arene framework by 1,3-alternate fashion and potassium metal ion is found to 1:1 by proton NMR spectroscopy and extraction equilibria. Association constants (log K-a) for I and 2 were determined to give 2.51 and 3.49, respectively. (C) 1998 Academic Press.

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收藏

页码：464 / 471

页数：8

相关论文

共 18 条

[1]

ANDREETTI GD, 1991, INCLUSION COMPOUNDS, V4, P64

[2] SYNTHESIS AND COMPLEXING PROPERTIES OF A DOUBLE-CALIX[4]ARENE CROWN-ETHER [J].

ASFARI, Z ;

ABIDI, R ;

ARNAUD, F ;

VICENS, J .

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1992, 13 (02) :163-169

[3] SYNTHESIS AND PROPERTIES OF DOUBLE-CALIX[4]ARENES, DOUBLY-CROWNED CALIX[4]ARENES, AND DOUBLE-CALIX-CROWNS [J].

ASFARI, Z ;

WEISS, J ;

PAPPALARDO, S ;

VICENS, J .

PURE AND APPLIED CHEMISTRY, 1993, 65 (03) :585-590

[4] DOUBLY CROWNED CALIX[4]ARENES IN THE 1,3-ALTERNATE CONFORMATION AS CESIUM-SELECTIVE CARRIERS IN SUPPORTED LIQUID MEMBRANES [J].

ASFARI, Z ;

BRESSOT, C ;

VICENS, J ;

HILL, C ;

DOZOL, JF ;

ROUQUETTE, H ;

EYMARD, S ;

LAMARE, V ;

TOURNOIS, B .

ANALYTICAL CHEMISTRY, 1995, 67 (18) :3133-3139

[5] SYNTHESIS, COMPLEXATION, AND MEMBRANE-TRANSPORT STUDIES OF 1,3-ALTERNATE CALIX[4]ARENE-CROWN-6 CONFORMERS - A NEW CLASS OF CESIUM SELECTIVE IONOPHORES [J].

CASNATI, A ;

POCHINI, A ;

UNGARO, R ;

UGOZZOLI, F ;

ARNAUD, F ;

FANNI, S ;

SCHWING, MJ ;

EGBERINK, RJM ;

DEJONG, F ;

REINHOUDT, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (10) :2767-2777

[6] COMPLEXATION OF ALKALI-METAL CATIONS BY CONFORMATIONALLY RIGID, STEREOISOMERIC CALIX[4]ARENE CROWN ETHERS - A QUANTITATIVE-EVALUATION OF PREORGANIZATION [J].

GHIDINI, E ;

UGOZZOLI, F ;

UNGARO, R ;

HARKEMA, S ;

ABUELFADL, A ;

REINHOUDT, DN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (19) :6979-6985

[7] COMPUTATIONAL STUDY OF THE STRUCTURAL, ENERGETICAL, AND ACID-BASE PROPERTIES OF CALIX[4]ARENES [J].

GROOTENHUIS, PDJ ;

KOLLMAN, PA ;

GROENEN, LC ;

REINHOUDT, DN ;

VANHUMMEL, GJ ;

UGOZZOLI, F ;

ANDREETTI, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (11) :4165-4176

[8]

Gutsche C.D., 1989, Calixarenes

[9] CALIXARENES-9 - CONFORMATIONAL ISOMERS OF THE ETHERS AND ESTERS OF CALIX[4]ARENES [J].

GUTSCHE, CD ;

DHAWAN, B ;

LEVINE, JA ;

NO, KH ;

BAUER, LJ .

TETRAHEDRON, 1983, 39 (03) :409-426

[10]

GUTSCHE CD, 1987, SYNTHESIS MACROCYCLE, P93